- Chilean senator from Maule Region (1993-2018).
- Son of jurist Hernán Larraín Ríos and Eliana Fernández.
- Graduated from Pontifical Catholic University of Chile with degree in Law.
- He was president of the Pontifical Catholic University of Chile Student Federation in 1969.
- Vice-rector's office of the Pontifical Catholic University of Chile until 1986.
- Member of National Television Council (aka CNTV) from 1975-1982.
- Was executive director of the foundation "Andes" from 1987-1991.
- Member of Superior Council of the Pontifical Catholic University of Chile from 1989-1991.
- He entered politics after the assassination of his friend and mentor Jaime Guzmán.
- Master of Laws degree at the London School of Economics.
- One of the co-founders of the financial company "Cooperativa La Familia" that went bankrupt in 1977.
- President of the Senate of Chile (2004-2005).
- President of the Chilean right-wing political party UDI from 2006-2008 & 2015-2017; vice-president from 1991-1997.
- Ex-father-in-law of actress Antonia Zegers.
- Minister of Justice and Human Rights by Chile's president Sebastián Piñera from 2018-2022.
- Member of the Expert Commission at the 2023 Chilean constituent assembly.
- Member of the Inter-American Dialogue since 2012.
- His great-grandmother, Teresa Talavera Appleby, was one a three Talavera Appleby sisters married with politician Eulogio Altamirano.
- His name, along with Jaime Guzmán, Andrés Chadwick and Carlos Bombal, was listed among the friends of the "Colonia Dignidad" of Paul Schäfer.
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