- Queen Regent of Spain (1886-1902).
- Mother of King Alfonso XIII.
- Great-great-great grandmother of Felipe Juan Froilán de Marichalar y Borbón, Victoria Federica de Marichalar y Borbón, Juan Urdangarín Borbón, Pablo Urdangarín Borbón, and Miguel Urdangarín Borbón.
- Great-grandmother of Juan Carlos de Borbón, Gonzalo de Borbón, Pilar de Borbón, and Alfonso de Borbón Dampierre.
- Grandmother of Alfonso de Borbón, Juan de Borbón, and Leandro Alfonso de Borbón. Leandro was her son's Alfonso's son by his mistress, Carmen Ruiz Moragas.
- Great-great-grandmother of Simoneta Gómez Acebo, Cristina de Borbón, Elena de Borbón, King Felipe VI of Spain, and María Zurita.
- Grandmother of Beatriz de Borbón y Battenberg.
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