- Got into acting as a way to overcome his stuttering problem.
- Served as the honorary chairperson of the Stuttering Foundation of America's Stuttering Awareness Week in 2001, 2002 and 2003.
- Enjoys baseball, camping, and spending quality time with family and friends. An early aspiration to play professional baseball was cut short after an arm injury in his teen years.
- He was Marley Shelton's high school prom date. He bought her 100 roses, wore a tux and drove a black convertible Mustang. Marley said that he "totally did it right".
- During the off-season of Buffy the Vampire Slayer (1997) Nicholas often grew a goatee, while brother, Kelly, stays clean-shaven. This often led to fans mistaking Kelly for Nicholas.
- Twin brother of Kelly Donovan. Nicholas is 3 minutes younger. He also has two younger brothers, Christian and Kyle Schultz.
- Still keeps in touch with his Buffy the Vampire Slayer (1997) co-star, Charisma Carpenter.
- Named #4 of the Top Ten Sexiest Men of the Buffy / Angel universe in a fan poll by the Buffy the Vampire Slayer fanzine (2004).
- Appeared with David Boreanaz (Angel), Kristine Sutherland (Joyce Summers), and Mark Lutz (Groosalugg) at the Angel And Buffy Convention held at the Brighton Centre in Brighton, England, 29 August, 2003.
- Attended Pasadena City College.
- Mother is talent agent Kathleen Schultz.
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