- Gave birth to her 1st child at age 33, a daughter Fianna Francis Masterson on February 14, 2014. Child's father is her husband, Danny Masterson.
- On the cover of 'Interview' magazine when she was 13, and shortly thereafter became the youngest model to ever appear on the cover of Vogue (she was on the Italian edition).
- Some songs on Sean Lennon's CD "Friendly Fire" are about their break-up.
- Named after the song 'My Petite Bijou' by Lambert, Hendricks and Ross. 'Bijou' means 'jewel' in French.
- The title of her album 'I'd Rather Eat Glass' is a reference to what she's rather do than go back to modeling.
- Champion equestrienne as a child.
- (October 18, 2011) Married her boyfriend of 7 years Danny Masterson following a 2-year-long engagement.
- No relation to actress Busy Philipps.
- An animal lover, Bijou owns two dogs and a horse. One is a white male Pekinese named Mama's Flea Angel Eyes (called Flea), which she got in 1996. The other is a black female Pek-a-Poo (a Pekingese/Poodle mix) named Sweet Pea (called Pea), which she got in early 2000 after convincing a journalist who was interviewing her to buy the puppy for her. Her horse is named Finnegan.
- Her father, born in Parris Island, South Carolina, had English and Irish ancestry.
- Along with Tara Reid, Paris Hilton, Nicky Rothschild, Kimberly Stewart, Lindsay Lohan, Nicole Richie & Kim Kardashian is one of Hollywood's most famous party girls.
- Was the January 2007 entry in Stuff magazine's 2006-2007 pin up calendar.
- Was a guest at Nicky Rothschild's Las Vegas wedding to Todd Andrew Meister.
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